University of Missouri Extension

WQ423, Revised April 1995

Monitoring Requirements for Biosolids Land Application

Ken Arnold
Chief of Land Application, Missouri Department of Natural Resources
John H. Dunn
Environmental Engineer, Environmental Protection Agency Region VII
Dennis Sievers
Department of Agricultural Engineering

Biosolids is a term for domestic wastewater sludge that meets standards for use as a fertilizer or soil conditioner. Biosolids standards include limitations for metals and other compounds, pathogen reduction, vector requirements and best management practices.

This publication outlines biosolids land application monitoring requirements.

Applying biosolids to land uses the available nitrogen, phosphorus and potash to fertilize growing crops. This is an environmentally sound practice sanctioned by the U.S. Environmental Protection Agency (EPA) and the Missouri Department of Natural Resources (DNR).

Reusing biosolids on crops, pastures and timberland reduces pollution of the waters of the state. It eliminates the environmental risks and costs associated with sludge disposal options, benefiting all citizens of Missouri.

Background

EPA regulations, under Title 40 Code of Federal Regulations Part 503 (40 CFR 503), establish the minimum national standards for the use and disposal of domestic sludge. These standards include limitations for the land application of biosolids.

The DNR has incorporated the EPA standards into the state requirements under the Missouri Clean Water Law and regulations. The state rules include additional requirements that are not covered in the EPA standards. Complying with state regulations automatically meets the EPA sludge standards.

Recommended minimum monitoring frequency

Monitor the biosolids to determine the quality for regulated pollutants listed in the biosolids standards. Base the number of samples on the quantity of sludge produced by the facility.

Another sampling plan may be approved for an equal number of samples per year. For example, you sample quarterly, but apply biosolids during July only. You may collect all four samples during the land application period (Table 1).

Table 1
Recommended monitoring frequency

Design sludge production
(dry tons per year)
Monitoring frequency (See notes 1 and 2.)
Metals, pathogens
and vectors
Nitrogen
TKN1
Nitrogen
PAN2
Priority pollutants and TCLP3
0 to 100 1 per year 1 per year 1 per month 1 per year
101 to 200 biannual biannual 1 per month 1 per year
201 to 1,000 quarterly quarterly 1 per month 1 per year
1,001 to 10,000 1 per month 1 per month 1 per week -- 4
10,001+ 1 per week 1 per week 1 per day -- 4
1Test total Kjeldahl nitrogen, if biosolids application is 2 dry tons per acre per year or less. 2Calculate plant available nitrogen, if biosolids application is more than 2 dry tons per acre per year.
3Priority pollutants (40 CFR 122.21, Appendix D, Tables II and III) and toxicity characteristic leaching procedure (40 CFR 261.24) is required only for permit holders that must have a pre-treatment program.
4One sample for each 1,000 dry tons of sludge.

Note 1
Total solids: A grab sample of sludge shall be tested one per day during land application periods for percent total solids. This data shall be used to calculate the dry tons of sludge applied per acre.

Note 2
Total phosphorus: Total phosphorus and total potassium shall be tested at the same monitoring frequency as metals.

Optional sampling for lagoons

If you own a wastewater treatment lagoon or sludge lagoon that is cleaned out once a year or less, you may choose to sample only when the sludge is removed or the lagoon is closed.

Test one composite sample for each 100 dry tons of sludge or biosolids removed from the lagoon during the year or left within the lagoon at closing. Composite samples must represent various areas at one-foot depth.

Sample type

Collect composite samples for all monitoring under this section. Each composite sample must consist of at least seven to 20 grab samples. Collect the samples during the same week from various locations in the sludge.

Data from individual grab samples may vary by as much as 50 percent from mean values. A composite sample made up of 20 grab samples will be 90 percent to 95 percent accurate.

Dry weight basis

Report all sample results on a dry weight basis unless otherwise specified. If the laboratory report does not specify dry weight, consider the data in a wet weight basis. The permit holder must convert the measurements to a dry weight basis. Use the following formula:

Wet weight in ppm or milligrams per kilogram ÷ Percent total solids/100

An example for 100 ppm at 2 percent total solids:

100 ppm ÷ 2/100 = 100 ÷ 0.02 = 5,000 ppm dry weight

Soil testing

Test soils for soil pH, cation exchange capacity and available phosphorus once every four or five years, if biosolids are applied during that period. Base available phosphorus on Bray's P-1 test.

Recommended soil testing methods must be in accordance with Recommended Chemical Soil Test Procedures for the North Central Region (North Dakota Agricultural Experiment Bulletin 499-Revised).

 

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